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The emergence of nanotechnologies aims at developing new composite materials. Nanocomposites based on graphene have generated intense interest among scientists because of their unique properties. The dispersion and interfacial interactions between the nanofillers and polymer matrix are essential to obtain improved properties of these nanocomposites. The physicochemical properties understanding of nanocomposites based on insulating or semiconductive polymers and graphene derivatives provides useful informations for their applications in various fields including the optoelectronics and fabrication of photovoltaic cells.